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You can choose what will happen if a shopper clicks an order button for an item they have already placed into their shopping cart.
By default, clicking the order button for an item in the cart will take the shopper back to the shopping cart without updating the item quantity. Depending on what you think the shopper's intentions would be, you can set the button to do nothing (returns to cart) or increment the item quantity (add another of the same item to the cart).